Api 5l x70 covers manufacturing types in seamless and welded erw, saw types, both applied for oil and gas transmissions. Investigation on acoustic emission of hydrogen induced cracking for carbon steel used in pressure vessel gongtian shen 1, lifei li 2, wanling zhang 2 1china special equipment inspection institute building 2, xi yuan, he ping jie, chao yang district, beijing, china tel. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogeninduced cracking susceptibility in different layers of a hot rolled x70. Hydrogen induced cracking test instrument is supplied with standard size of 12l x 12w x 9h. Hydrogen induced cracking tests of high strength steels. Hydrogen induced cold cracking in a low alloy steel. Atomic hydrogen is a product of the cathodic reaction, they would diffuse inside the metal pipe. Hydrogen induced crackinghydrogen induced cracking 2. Hydrogeninduced cracking in martensitic highstrength steels. The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. Hydrogen gas introduced thinning thinning main crack main crack microcrack formed crack linkage.
It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. Sources of hydrogen hydrogen came from the lsaw steel pipe micro crack, inside the battery cathode process. The results indicate that flow control valve body failed due to combination of hydrogen induced corrosion cracking hicc and sulfide stress corrosion cracking sscc. Pdf hydrogen assisted cracking and co 2 corrosion behaviors of.
Susceptibility to hydrogeninduced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the. This is hydrogen induced cracking by synergis education on vimeo, the home for high quality videos and the people who love them. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Each form can build up enough pressure to produce internal cracks. Corrosionpedia what is hydrogeninduced cracking hic. Hic test, hydrogen induced cracking test, step wise.
Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Hydrogen blistering occurs when hydrogen atoms diffuse into the steel, and hydrogen gas nucleates at internal defects and inclusions, forming voids which eventually generate enough pressure to locally rupture the metal. The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to. Hydrogen induced stress cracking hisc and dnvrpf112.
Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. Metallurgical factors in stress corrosion cracking scc and. Hydrogen cracking its causes, costs and future occurrence. Also called l485 pipe, as its yield strength minimum in 485 mpa 70,300 psi. Hydrogen damage takes place at two temperature regions, elevated temperatures and temperatures at ambient. Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999. Sulfide stress cracking ssc vs hydrogen induced cracking. Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. Hydrogen cracking may also be called cold cracking or delayed cracking. Evaluation of hydrogeninduced cracking in highstrength steel. Journal of iron and steel research international 22. Similar to thermal desorption measurement, tep is a potential method in analyzing hydrogen traps of solid solution, dislocations and irreversible traps.
The specimens were immersed into the synthetic sea water saturated with h2s. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. Effective factors for the stress corrosion cracking scc crack initiation in pipeline steels. Comparative study of the behavior of api 5lx65 grade. Hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Metals free fulltext effects of different parameters on initiation. Hydrogen induced stress cracking hisc resistance and. According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217 wc9. Hydrogen induced cracking tests were conducted on high strength steels and nickeliron base alloys using the constant displacement boltloaded compact specimen.
Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. The inclusion of this reaction in the embrittlement process is. In this issue, the characteristic features and principal causes of hydrogen cracks are described. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogen induced cracking hic on steel for corrosion. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments.
It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress corrosion cracking and hydrogen induced. Hydrogen induced cracking test tank test methods nace tm0284 astm g39 material of construction polypropylene, pvc, or glass capacities up to 55 liters cortest offers a variety of different hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on a metal sample in a hydrogen enriched. When the crystal lattice is in contact or is saturated with atomic hydrogen, the mechanical. Understanding and mitigating hydrogen embrittlement of steels. The fracture morphology and hydrogen induced cracking can be explained by combined hydrogen embrittlement mechanisms. Since hydrogen induced crack generally occurs at a low temperature, below approximately 100 c 1, it is also called cold cracking to. Hydrogeninduced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. The hydrogen induced cracking hic of asrolled steels has been investigated. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. A53 and american petroleum institute api 5l pipe and astm a36 structural steel are examples of semikilled steels.
Investigation on acoustic emission of hydrogen induced. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. A106, being a killed steel, is suitable for some sevices with hydrogen present while a53 is not. Stress orientated hydrogen induced cracking sohic is a manifestation of sulfide stress cracking. Oriani 153 proposed a model where a local equilibrium of hydrogen in the. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Unkilled versus killed steel continues to be important in. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. Request pdf metallurgical factors in stress corrosion cracking scc and hydrogeninduced cracking hic nonmetallic inclusions can affect resistance of. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. Pdf in this study, hydrogen induced cracking hic, sulfide stress corrosion cracking sscc and hydrogen embrittlement he were carried out to study.
The kinetic and mechanical aspects of hydrogeninduced failure in. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Naceastm g193 1 includes the following description of hydrogen blistering. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Api 5l x70 pipe is a premium grade piping material in api 5l standard specifications. Hydrogen trapping sites and hydrogeninduced cracking in. A comparative study of hydrogeninduced cracking resistances of.
Hydrogen embrittlement is a complex phenomenon, involving. Api 5l x65 steel is the most widely accepted material for these types of pipes, which require a special limits of formability and strength. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Since hydrogeninduced crack generally occurs at a low temperature, below approximately 100 c 1, it is also called cold cracking to. Measurement of hydrogen induced cracking behaviour of weld specimens. Sulfide stress corrosion cracking ssc, nace tm 0177. The hic may promote one mode of fracture in an alloy rather than another form normally observed in benign environments. Hic testing apparatus is provided with specially made rack to keep the samples with minimum surface contact and all the specimens can be viewed during the test period easily. The presence of hydrogen atoms in a metal degrades some of its mechanical properties, especially its ductility, leading in some cases to embrittlement. Area fraction of recrystallized, substructured and deformed. Initiation of stress corrosion cracking and hydrogen. Hydrogen induced cracking hic in the oil and gas industry. Because hydrogen embrittlement limits the use of martensitic steels at high.
Hydrogen induced cracking hic from advanced ndt solutions. By using dent specimen, hydrogeninduced cracking hic cracks were found to initiate at martensiteaustenite interfaces and then. Hydrogeninduced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. For haz hydrogen cracking to occur, it is necessary for the hydrogen to migrate into the heat affected zone, which takes time. Hydrogen induced cracking hiccauses and prevention. Hydrogen traps and hydrogen induced cracking in 20crmo. Additionally, hydrogen atoms diffuse through metals and coalesce.
A53b vs a106b pipelines, piping and fluid mechanics. Hydrogeninduced cracking is a subset of stress corrosion cracking, and as i mentioned hardness must be below 22 hrc scale for anhydrous ammonia, so pwht is necessary. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. Hydrogeninduced cracking was studied in two steels used for the manufacture of. In refineries, both a53 and a106 are common for non corrosive services up to about 750 deg. Mechanical properties and hydrogen induced cracking. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hydrogeninduced cracking an overview sciencedirect topics. Specificationsgrades asmeastm saa 516 grades 606570. Hydrogen induced cracking hic there are a variety of forms of wet h2s cracking. Carbon steel a106 gr b pipes and tubes specification. It contains two product specification levels psl1, psl2. A comparative study of hydrogeninduced cracking behavior in api 5l x60 and x70. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering.
A new approach to the problem of hydrogen induced cold cracking in weldments of quenched. Hydrogen induced blistering when hydrogen is absorbed into metal and diffuses inward, it can precipitate as molecular hydrogen, at laminations, or inclusionmatrix interfaces. Hydrogen induced cracking is associated with absorption of hydrogen and a delayed time to failure incubation time during which hydrogen diffuses into regions of high triaxial stress. Susceptibility to sohic for linepipepressure vessel steels twi. The scc cracks are those cracks which are induced due to the combined effects of a corrosive environment and. Hydrogen induced cracking steel features, applications. Effect of microstructure on hydrogeninduced cracking of. Hydrogen embrittlement and stress corrosion cracking. Refers to mechanical damage of metal caused by the presenceinteraction with hydrogen can be classified in to following types 1 hydrogen blistering 2 hydrogen embrittlement 3 hydrogen attack 4 decarburization hydrogen damage.
This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Defects hydrogen cracks in steels identification twi. Particularly common to the oil and gas industry where the use of steel. Weld metal hydrogen cracking in pipeline girth welds, proc. Hydrogen induced cracking hic pipe corrosion reactions occur far beyond the rolling offered, welding.
1242 511 254 267 1521 1062 1266 225 1249 31 791 907 1405 1291 1479 113 622 1263 859 4 513 1141 1430 3 1223 1172 224 1223 619 957 1368 1156 1264 84 797 182 468 374